IMO there are better alternatives. I tried the freebie demo from Amplesound and subsequently deleted it from my sample drive. And I don't delete very many things.
EAG from Orange Tree Samples is an excellent product, for $150 IIRC, and would be my first choice. Lots of expressive possibilities, and very credible-sounding. Another very good choice would be the
Elya Efimov acoustic guitar, which is currently on sale for 75 euros.
If your acoustic guitar needs are modest, e.g. not a featured instrument but more rhythm/background support, a real bargain (at a mere $40!) is the
Acoustic Guitar Collection from Indiginus. Highly recommended, even if it's not quite up there with the aforementioned libraries.