It depends when you're looking for - yes, you can record both tracks at the same time as people have outlined above, but they'll sound exactly the same - if you use different sounds, that certainly helps mix it up a bit.
If you use the method described above to nudge one track over a bit, so there's just slightly different from eachother, that will fatten things up a bit more.
I personally prefer to actually recording the tracks separately - the subtle nuances in recording it a second time will distinguish it from the first guitar track and make it sound the most natural and biggest (IMO).
Russ