Yeah, the UA-25EX which is the previous model has the same problem. It's really annoying. I just unplug the cables from the back of the interface and make sure they aren't touching on something so it humms... Too much hassle to reach around the back and turn them off all the time...
One solution would be to make a toggle box which comes out of the back and sends one signal to your monitors, but with the flick of a switch, sends the other to your headphones. I don't know enough about the voltages and stuff going on in there though to know if you can do that passively (without power)... It might need an additional amp for the headphones. But you could probably test it by just plugging in your headphones into the L or R 1/4" on the back and see if you get plenty of volume. At the very least, a simple 'switch' which just turns the signal off to the speakers would be easy and cheap to build. Just stick it onto the top of your interface..
Maybe someone with some better electrical knowledge could let us know if this could be build easily with a simple switch and without the need for amps and a circuit and all that...?