Notice I put 'fixed' onto the threat title and not 'solved'. I will share what happened here, I am delighted because I can now complete the final edits and plan to put it on the songs forum very soon now.
Basically I found the problem by going through the entire signal chain in my track. From balances on individual tracks, checking interleaves, busses, interleaves on busses, soloing them all in turn, checking outputs from VST's including Channel Tools on an acoustic guitar bus and Guitar Rig on a lead guitar bus.
I finally get to the master bus, still everything seemed OK, but realised that there was one more stage in the X2 signal chain, which was the interface outs. Even with the console view across 2 monitors, I couldnt find them, and hadn't seen them for a long time. By clicking and dragging on the right edge of the console, I found the three sets of outs for my audio interface, and lo and behold, the main outs were not locked together and the left channel was set 6 to 7 dB higher than the right channel ! I locked and fixed them, performed another bounce to tracks, and finally, both the waveform and the playback were back in balance. Total Joy of course. I also know how this happened. A few nights ago, I was fiddling with ACT and my sliders on my PCR-500, and when I was controlling the busses, I worked one slider which didn't appear to be attached to any parameter, after waddling it about for a minute or so, I though best to leave it alone and attempted to put it back in the position I found it, correctly as it turned out, thinking I might be changing a parameter I had simply failed to see. I will have to go back and experiment, but it is almose certain that it was controlling the left channel of the main outs, which were permanently hidden to me at that point...one big mystery solved.
However, this poses a strange conundrum. Why did my playback sound balanced when I played through the normal project with all tracks, yet only appeared left biased when I bounced down? I tryed bouncing down both from the master channel (ie before the outs) and from the outs, and got the same, off centered sonic results each time. I also did try an export from selecting all the tracks to a wav file, and this was also left biased now. Surely by logic, if I had mixed 'compensating' for my left out being raised, putting the outs in sync again would then make the project right biased during playback. However, no, it still plays back with the stereo balance intact. This seems to defy all logic, unless someone has a decent explaination.
However, I am delighted to understand what happened and fix it, albeit scratching my head as how I got the results I did... I think this is worth sharing for future forum searches however because the main outs are so often out of sight and out of mind, that I can see how it would be possible for anyone to accidently move them on a control surface (particularly if they are included in an ACT preset) and hear the consequences without it being obvious where the problem subsequently lay.
Hope this helps and thanks for your suggestions guys.
Garry Kiosk