As was mentioned already if you wanted to hook up multiple interfaces you would have to switch to a driver mode other than ASIO. However if you are just looking to add extra inputs and you have two interfaces with optical connectors then you can daisy chain them. One would be the actual interface communicating with your computer (master) and the second would just use the optical connector to send extra channels to.
For example... I've got a Layla Echo 3G which has optical in/out. I also have a Focusrite Scarlett 18i6 which has an optical in (but no out). The optical in on the Scarlett gives me 4 extra channels (above and beyond the multi ins and analog ins it already has) at up to 96k (I think) and 8 extra channels at 44.1k. So in theory I can use an optical cable from the output of the Layla to the input of the Scarlett and then use the 8 analog inputs on the Layla which combined with the inputs on my Scarlett give me a total of 16 analog inputs at 44.1k (not counting the SPDIF on the Scarlett).
The optical connector will sometimes be labeled ADAT.
Whether all this works? Well IDK... I haven't tried it yet but it's supposed to.