What about the differences in the internal clocks of each will that cause sync issues?
FWIW, It's a PITA to try and get two different make audio interfaces to sync/operate as one.
By definition, it's not possible via ASIO.
Thus, you have to use WDM (which works well with some audio interfaces... less so with others... especially if you plan to work at ultra low latency)... AND you need to clock sync the two units (ie: via S/PDIF).
If you don't have the two units clock-synced, they will drift apart over time.
The longer the tune, the more drift you'll experience.
One rock-solid unit that suits your needs is a FAR better option.