For amp cab sims, I highly recommend cag IRs. Redwirez has a ton of real good ones. Same cabinet, different mics with different mic placements.
If you can't get a good cab sound out of one of these, it isn't the cab that is the problem.
On another note, the problem I have with DI'ed guitar recording through simulators, is the relationship between the signal attack and the sense of air. DI'ed guitars always give me too much attack as part of the overall volume and by the nature of the method, there is little you can do about it.
With a LIVE rig, and mic placement, the attack portion volume is naturally taken care of but the real signal chain.
Just my point of view and why I have moved more to LIVE tracking than using DI's and sims.
Jim