Lowest possible round-trip latency is not the Apollo's forte'.
The onboard Unison DSP is really nice (monitor/track in realtime thru UAD plugins with ~2ms latency), but the downside is that DSP support adds latency.
Apollo can get down to about 3.7ms total round-trip latency.
Apollo won't let you select the 32-sample ASIO buffer size if you're working above 48k.
Frankly, even if you could select the 32-sample ASIO buffer size at higher sample-rates, the audio would glitch.
If you're wanting to trigger drum samples at the lowest possible latency, right now, the best option is to run the Presonus Quantum (via Thunderbolt-3).
Round-trip latency at 96k (32-sample ASIO buffer size) is 1ms.
Triggering your drum samples would be one-way Playback latency (a little more than half a ms).
As long as your machine can keep up with the load, audio is completely glitch-free.
The only downside to Quantum; it doesn't have any onboard DSP for monitoring/routing/loopback-recording.
All monitoring/routing has to be done via software.
The lack of onboard DSP allows Quantum to yield such low round-trip latency.