Well I see that the symphony series from NI is getting no love in this thread. However, I use it quite a bit. Regarding the strings, it's my favorite library for legato strings and portamento. And the auto-divisi is a great feature.
The Brass Ensemble I use a lot for slow brass chords. The french horns can also do great soaring melodies when you want something a little less epic than Metropolis Ark.
Both libraries were just updated by the way.
The brass melodies in the song below are Sym Series Brass Ensemble. The string melody at the very end is Sym Series String Ensemble. (the other strings are NI Emotional Strings).
https://soundcloud.com/artturnermusic/evil-lurks-behind-innocence