Sony says this:
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Disc-at-Once should be used primarily with recording audio discs. Disc-at-Once is designed to eliminate the 2 second gap that is between the audio tracks on an original audio CD after it is recorded. If you choose the Disc-at-Once feature during the recording process, the final copied CD will not have the 2 second gap in between tracks and the music will be continual play. Not all CD recorders support Disk-at-Once. Track-at-Once can be used for both data and audio discs. Track-at-Once keeps the 2 second gap between the audio tracks. When recording in Disc-at-Once mode the laser on the drive stays on continuously while during the Track-at-Once mode recording, the laser will turn off and on in between the tracks.
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In another source, I read that you should not use Track at Once if you are sending the CD off for manufacture because there could be clicks between tracks. If that is correct, then the whole CD should be assembler in Sonar or in another tool with the gaps (or lack of gaps) between songs however you want them, and then the CD should be written as Disc-at-Once.