Between the free Kontakt Player factory library, and the Sampletank free (Custom Shop) factory library, you can get some useful instruments right off the bat for free.
In the Kontakt Player Band section, you get a few basses, electric piano, jazz guitar, jazz organ, rock guitar, and a few drum kits. There are also some vintage, synth, and world sounds. If you upgrade to the full version, you will have endless opportunities to buy more expansions. Some expansions are even available for the Player version, without requiring the purchase of the full Kontakt version.
https://www.native-instruments.com/en/products/komplete/samplers/kontakt-5-player/kontakt-factory-selection/ In Sampletank free (Custom Shop) you get a grand piano, violins, flute, pop brass, electric pianos, tonewheel organ, acoustic & electric guitars, a P-Bass and a J-bass, and some synth sounds. I think the SampleTank guitars and basses as well as the acoustic instruments, sound very realistic.
http://www.ikmultimedia.com/products/sampletankcs/ These are decent sounds to get started with, and both are fully functional. Start with these and then decide what you are lacking. The advantage to either of these is that they are both multitimbral, so you can setup multiple instruments in each plugin instance.