Visting this forum last night after the session reminded me of the update, so I went back to the studio computer and proceeded to do it during the night not to lose any time.
Download of ST 3.5 and the library update (around 1.47 GB IIRC) took less than 5 minutes.
No issue whatsoever during installation. The library update even pointed to the correct (custom) folder. No authorization issue.
I then launched ST in standalone mode so that it could do its indexing thing, which took a while - I'd say maybe between 10-15 minutes. I do have all the other ST instruments/libraries and a couple of Sonic Reality add-ons, so I guess it's a lot to scan.
Haven't tested the new functionalities or the CS. As for the library, I'm using ST very sporadically, only for a couple of patches (electric Basses and, irregularly, a couple of Miroslav patches) so I couldn't tell.