Volcano has full modulation capabilities, Pro-Q has none. You can drive Volcano from an envelope follower, an envelope generator or a sophisticated tempo-synced LFO. It allows you to radically alter the tone of pretty much anything, or add a rhythmic component to it.
If your genre is orchestral film scores, then Volcano might not be particularly useful to you. But if you're doing EDM, electronica or experimental music and you like to get technical, it could be an excellent creative tool.