Some options for something other that Electric Bass Guitar or synth bass.
Boulder Sounds
Guitarron I really like this one.
Ilya Eftimov -
Contrabass Balalaika - another different sounding acoustic bass instrument.
Acoustic Samples
AkousKontr - This is an upright bass for UVI workstation. I bought the Kontakt version before the discontinued it and switched to UVI, its the best upright I have. They also had an electric version but they do not seem to have ported that to UVI.
I have not found much in the way of acoustic bass guitars for Kontakt. There is a reasonable one in the
Independence Pro factory library. In fact all the electric and acoustic basses are good, its the old yellowtools "Majestic" package, not full featured like Scarbee or Orange Tree but they sound nice. Unfortunatly apart from a couple of minor updates development of Independence seems to have stopped since Magix took over. It a shame because the factory library is better than both Kontakt's and Sample Tank 3 in many areas. (Sax, Bass and the Kirk Hunter orchestral stuff).