I only have the default library, so I've not tried this, but here's what the manual says:
Superior Drummer® supports all current Toontrack sound sets as well as legacy SUPERIOR libraries. You can access ANY instrument from ANY library via a sophisticated system of X-Drums, mixing and matching instruments with no limitation. You can even specify which microphones to use for the external kit pieces! That tells me you can indeed mix and match instruments, even from EZDrummer libraries, and that the X-Drums section is the gateway for all of that. Page 29 of the manual appears to explain how to do it.