I started my adventures with virtual orchestras with GPO (actually GOS, but that was just strings). I learned quite a bit from my time using it.
But both my ears and the world of sampled instruments have matured over the the last dozen of so years.
I still recommend GPO and JABB as excellent training tools, but I also suggest that they may not be all that useful as your orchestration and arrangement skills improve. If you can swing it I think it makes sense to consider more modern libraries, even as a starting point.
Instant Orchestra, on the other hand, left me somewhat underwhelmed. Maybe at $115, but there are so many similar libraries that are considerably more up to date. Think about tools from Sonokinetic, Project Sam or Spitfire, depending on your budget. I think you'll get a lot more mileage from the newer tools.