I don't even have Native Instruments Komplete. I have Kontakt and that's about it. (Well, I have Guitar Rig 5, but don't use it).
Nevertheless, I have a Komplete Kontrol S61 and couldn't be happier with a controller keyboard. Great touch on the keys, the touch strip mod wheel is very nice. The keyboard/controller has useful, easy to understand features. The sustain pedal works just as I hoped. Playing Addictive Keys with it is a joy. It's great.
The light guide works with Kontakt and with the sample set of Komplete software that Native Instruments throws in with the purchase. Third party libraries also work in Kontakt with the light guide.
Someday I'll save up enough to splurge and actually get Komplete.